dc.description.abstract |
As the Knudsen number (de ned as the as the ratio of the molecular mean free path length to length scale of the device) increases, materials' thermal properties are compromised due to disruption of phonon movement. If the thermal conductivity and mean free path relationship of the phonons is known, interference of size e ects at small scales can be predicted as well as thermal conductivity reductions. To do this, thermal accumulation spectra of four wurtzite semiconductor materials: gallium nitride, aluminum nitride, aluminum gallium nitride, and beta form gallium oxide were calculated at di erent temperatures. As these materials are usually employed in high power electronic applications in con ned structures, a method was devised in order to infer their conductivities at small scales from accumulation spectra. Third-order force constants, which are the expanded coe cients of crystal ground energy, are used directly for mentioned calculations.It was observed that this approach is very useful at high anharmonicity where MFP range is short and temperature is high. This work concluded that MFP spectra contributing to thermal conductivity were 1661.7 nm, 1648.8 nm, 442.3 nm and 467.3 nm respectively for GaN, AlN, AlGaN and -form Ga2O3 at 300 K. Hence, size e ects are expected to dominate conductivity at scales smaller than these values. |
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