dc.contributor |
Graduate Program in Chemistry. |
|
dc.contributor.advisor |
Bulak, Ece. |
|
dc.contributor.author |
Ünal, A. Özge Akdeniz. |
|
dc.date.accessioned |
2023-03-16T11:00:29Z |
|
dc.date.available |
2023-03-16T11:00:29Z |
|
dc.date.issued |
1999. |
|
dc.identifier.other |
CHEM 1999 Un11 |
|
dc.identifier.uri |
http://digitalarchive.boun.edu.tr/handle/123456789/14327 |
|
dc.description.abstract |
In this study the reaction of 16 e- system, dichlorobiscyclopentadienyl- zirconium(IV) with N-containing, S-containing and thioamide containing ligands were studied. In the presence of a non-coordinating solvent, CH2Cl2, thioacetamide coordinated to Cp2ZrCl2 through C=S unit with participation of the NH group. This complexation was proved by the new bands appearing in Zr-N and Zr-S stretching region, also by the blue shift of thioamide band I and the red shift of thioamide band IV of thioacetamide. Deprotonated ethanethiol with Cp2ZrCl2 gave a dimeric complex with the formula (Cp2ZrClSCH2CH3)2. Without deprotonation ethanethiol did not coordinate to Cp2ZrCl2. |
|
dc.format.extent |
30 cm. |
|
dc.publisher |
Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 1999. |
|
dc.subject.lcsh |
Heterocyclic compounds. |
|
dc.title |
Reactions of dichlorozirconocene with nitrogen containing heterocycles and related compounds |
|
dc.format.pages |
xv, 76 leaves; |
|