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Reactions of dichlorozirconocene with nitrogen containing heterocycles and related compounds

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dc.contributor Graduate Program in Chemistry.
dc.contributor.advisor Bulak, Ece.
dc.contributor.author Ünal, A. Özge Akdeniz.
dc.date.accessioned 2023-03-16T11:00:29Z
dc.date.available 2023-03-16T11:00:29Z
dc.date.issued 1999.
dc.identifier.other CHEM 1999 Un11
dc.identifier.uri http://digitalarchive.boun.edu.tr/handle/123456789/14327
dc.description.abstract In this study the reaction of 16 e- system, dichlorobiscyclopentadienyl- zirconium(IV) with N-containing, S-containing and thioamide containing ligands were studied. In the presence of a non-coordinating solvent, CH2Cl2, thioacetamide coordinated to Cp2ZrCl2 through C=S unit with participation of the NH group. This complexation was proved by the new bands appearing in Zr-N and Zr-S stretching region, also by the blue shift of thioamide band I and the red shift of thioamide band IV of thioacetamide. Deprotonated ethanethiol with Cp2ZrCl2 gave a dimeric complex with the formula (Cp2ZrClSCH2CH3)2. Without deprotonation ethanethiol did not coordinate to Cp2ZrCl2.
dc.format.extent 30 cm.
dc.publisher Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 1999.
dc.subject.lcsh Heterocyclic compounds.
dc.title Reactions of dichlorozirconocene with nitrogen containing heterocycles and related compounds
dc.format.pages xv, 76 leaves;


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