Reactions of dichlorozirconocene with nitrogen containing heterocycles and related compounds

dc.contributor	Graduate Program in Chemistry.
dc.contributor.advisor	Bulak, Ece.
dc.contributor.author	Ünal, A. Özge Akdeniz.
dc.date.accessioned	2023-03-16T11:00:29Z
dc.date.available	2023-03-16T11:00:29Z
dc.date.issued	1999.
dc.identifier.other	CHEM 1999 Un11
dc.identifier.uri	http://digitalarchive.boun.edu.tr/handle/123456789/14327
dc.description.abstract	In this study the reaction of 16 e- system, dichlorobiscyclopentadienyl- zirconium(IV) with N-containing, S-containing and thioamide containing ligands were studied. In the presence of a non-coordinating solvent, CH2Cl2, thioacetamide coordinated to Cp2ZrCl2 through C=S unit with participation of the NH group. This complexation was proved by the new bands appearing in Zr-N and Zr-S stretching region, also by the blue shift of thioamide band I and the red shift of thioamide band IV of thioacetamide. Deprotonated ethanethiol with Cp2ZrCl2 gave a dimeric complex with the formula (Cp2ZrClSCH2CH3)2. Without deprotonation ethanethiol did not coordinate to Cp2ZrCl2.
dc.format.extent	30 cm.
dc.publisher	Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 1999.
dc.subject.lcsh	Heterocyclic compounds.
dc.title	Reactions of dichlorozirconocene with nitrogen containing heterocycles and related compounds
dc.format.pages	xv, 76 leaves;