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A computational analysis of solvent effect :|thiol-ene reactions and CaO bond strength within hydrated calcium clusters

Munar, İpek. (Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2020., 2020.)

In the first part this thesis, the solvent effect on thiol-ene reaction kinetics is elucidated. The effect of polar media on the reaction kinetics is taken into account by using the transition state theory, the reactivities ...
(BIS) phosphonate functionalized polymeric materials for biomedical applications

Altuncu, Merve Seçkin. (Thesis (Ph.D.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2022., 2022)

This work describes synthesis, characterization, and evaluation of (bis)phosphonate functionalized monomers, macromers and crosslinkers as well as their polymers and crosslinked networks for biomedical applications such ...
Development of reactive phosphonate and phosphonic acid-contaning methacrylates

Edizer, Seda. (Thesis (M.S.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2010., 2010.)

Four novel phosphonated methacrylate, two novel phosphonic acid-containing methacrylate and one phosphate-containing methacrylate monomers have been synthesized using three different routes and studied for their potential ...
Difunctional monomeric and polymeric photoinitiators: synthesis and photopolymerization behaviors

Cesur, Belgin. (Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2014., 2014.)

The first methacrylate monomers with two Type I or Type II side-chain photoinitiating groups (PI1, PI2 and PI3) have been synthesized from reactions of 2-(chloromethyl)acryloyl chloride and 4-hyroxybenzophenone, ...
Experimental and computational investigation of structure- reactivity relationship of methacrylates

Karahan, Özlem. (Thesis (Ph.D.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2012., 2012.)

In the first part of this work, a series of alkyl α-hydroxymethacrylates (RHMA) were synthesized and computationally modeled in order to understand the structure-reactivity relationships in their polymerizations. Several ...
Phosphonate and bisphosphonate - functionalized poly (B-amino ester)s and polyethylenimines for biomedical applications

Tatlıyüz, Mirac. (Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2017., 2017.)

In the first part of this study, phosphonate/bisphosphonate end-modified poly(βamino ester)s (PBAEs) are synthesized and their pH sensitivity and drug delivery properties are investigated. Synthesis of the polymers involves ...
Photohysical and photochemical studies novel thioxanthone-functionalized methacrylates

Eren, Tuğçe Nur. (Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2015., 2015.)

Five novel thioxanthone (TX) based monomeric photoinitiators (PIs) for free radical polymerization of acrylates were synthesized from reactions of tert-butyl α-bromomethacrylate with 2-hydroxy thioxanthone (TX1) and ...
Stimuli responsive functional polymeric materials for biomedical applications

Demirer, Hatice Betül. (Thesis (Ph.D.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2019., 2019.)

This work consists of synthesis, structural characterization and evaluation of stimuliresponsive functional polymers and hydrogels designed for biomedical applications. In the first project pH and redox responsive degradable ...
Synthesis and evaluation of new bisphosphonate - functionalized (METH) acrylates for biomedical applications

Güven, Melek Naz. (Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2016., 2016.)

In the first part of this work, new urea dimethacrylates functionalized with bisphosphonate ( 1 a, 1 b) and bisphosphonic acid (2a, 2b) groups were synthesized and evaluated for dental applications. Monomers 1a and 1 b ...
Synthesis and evaluation of novel phosphonated and bisphosphonated methacrylates with possible environmental and biomedical applications

Bilgici, Zeynep Saraylı. (Thesis (Ph.D.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2013., 2013.)

In this study, a series of mostly alkyl α-hydroxymethacrylate (RHMA)-derived novel monomers in four groups, and polymers of some of them were synthesized for various purposes including dental, bone-targeting and metal-binding ...
Synthesis and photopolymerization of new phosphorus containing dental monomers

Bilgici, Zeynep Saraylı. (Thesis (M.S.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2006., 2006.)

Novel crosslinkers with phosphonate, phosphonic and carboxylic acid functions were prepared for use in dental materials. The crosslinkers were based on t-butyl - bromomethacrylate (TBBr) and synthesized by two different ...
Synthesis and photopolymerization of novel ALKYL-a- hydroxymethyl acrylate based dental crosslinking monomers

Yağcı, Mustafa Barış. (Thesis (M.S)-Bogazici University.Institute for Graduate Studies in Science and Engineering, 2005., 2005.)

The most commonly used dental restorative filling composites are composed ofBisphenol A glycolate dimethacrylate (Bis-GMA) monomer, an inorganic filler, and apolymerization initiator system. A comonomer such as triethyleneglycol ...
Synthesis and photopolymerizations of new dental monomers from o-hydroxyaryl phosphonates

Şahin, Görçin Görkem. (Thesis (M.S.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2008., 2008.)

New phosphonate, phosphonic and carboxylic acid containing monomers were synthesized from o-hydroxyaryl phosphonates and dimethyl 2-hydroxyethyl phosphonate for use in dental adhesives and composites. First set of monomers ...
Synthesis and photopolymerizations of new methacrylate crosslinkers and antibacterial quanternary ammonium monomers

Ayfer, Burcu Sunam. (Thesis (M.S.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2004., 2004.)

In the first part of this work, new amine monomers were synthesized from the reaction of 3-(acryloyloxy)-2-hydroxypropylmethacrylate (AHM), acrylamide and methacrylamide with various amines and then reacted with various ...
Synthesis and polymerization of new phosphonated monomers for dental applications

Yeniad, Bahar. (Thesis (M.S.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2008., 2008.)

Three novel phosphonated monomethacrylate monomers have been synthesized and studied for their potential use as monofunctional reactive diluents in dental materials. The monomers are based on glycidyl methacrylate (GMA) ...
Synthesis and polymerizations of (BIS)phosphonated - (BIS)methacrylamides for dental applications

Akgün, Burçin. (Thesis (M.S.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2012., 2012.)

In the first part of this work, novel phosphonate and phosphonic acid-containing bis(methacrylamide)s (1 and 2) were synthesized by amidation of 2-(2-chlorocarbonyl-allyloxymethyl)-acryloylchloride with diethyl ...
Synthesis and polymerizations of novelbisphosphonate- containing methacrylates

Büyükgümüş, Özlem. (Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2012., 2012.)

In this study, two novel bisphosphonate-containing methacrylates (1 and 2) were synthesized from reaction of ethyl and tert-butyl -bromomethacrylates with 3,3-bis(diethoxyphosphoryl)propanoic acid. Their photopolymerizations ...
Synthesis and polymerizations of phosphonated - (METH) acrylates and (METH) acrylamides

Altın, Ayşe. (Thesis (M.S.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2012., 2012.)

In the first part of this work, three phosphonate containing (meth)acrylamides (1-3) were synthesized. Monomers 1 and 3 were synthesized by amidation reaction of acryloyl chloride with diethyl amino(phenyl)methylphosphonate ...
Synthesis of new dental adhesive monomers and polymers

Albayrak, Aylin Ziylan. (Thesis (Ph.D.)-Bogazici University. Institute for Graduate Studies in Science and Engineering, 2006., 2006.)

New phosphonate, phosphonic acid, carboxylic acid, iminodiacetate containing adhesive monomers based on alkyl-hydroxymethyl acrylates and their derivatives were synthesized. A new phosphonate-containing cyclic monomer was ...
Synthesis of photopolymerizable macromers giving novel poly (B-amino ester)s for biomedical applications

Akyol, Ece. (Thesis (M.S.) - Bogazici University. Institute for Graduate Studies in Science and Engineering, 2016., 2016.)

Biodegradability, hemocompatibility, protein adsorption resistance, and strong interactions with hydroxyapatite (HAP)-based tissues such as dentin, enamel, and bone are properties that make phosphorus-containing biomaterials ...

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